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ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
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| Paper Title: | Pyridinium Dichromate Oxidation of Active Methylene Compounds - A Kinetic Study |
| Authors Name: | Umakant Sahu , Nagmani Manikpuri |
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IJRTI_185783
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| Published Paper Id: | IJRTI2303122 |
| Published In: | Volume 8 Issue 3, April-2023 |
| DOI: | |
| Abstract: | Pyridinium dichromate in aqueous methane carboxylic acid in presence of mineral acid, oxidizes active methylene compounds such as acetyl acetone and benzoyl acetone to the corresponding pentane-2,3,4-trione and 1-phenyl, butane-1,2,3-trione. The (-dc)/dt is proportional to the concentrations of first power of Pyridinium dichromate(PDC) oxidant, and H+ ions. The reactions being nearly first to zero order in substrates, while on the contrary rection completely fails to induce polymerisation of acrylonitrile. The kinetic data evaluated can be correlated with a proposed mechanistic route, involving the intermediate formation of complex at symmetrical transition state in rate determining step, which undergoes decomposition to yield the products. |
| Keywords: | Acetyl acetone, benzoyl acetone, pyridinium dichromate, oxidation, kinetics. |
| Cite Article: | "Pyridinium Dichromate Oxidation of Active Methylene Compounds - A Kinetic Study", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 3, page no.698 - 703, April-2023, Available :http://www.ijrti.org/papers/IJRTI2303122.pdf |
| Downloads: | 000205110 |
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2303122
Registration ID:185783
Published In: Volume 8 Issue 3, April-2023
DOI (Digital Object Identifier):
Page No: 698 - 703 Country: -, -, India Research Area: Chemistry Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2303122 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2303122 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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