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International Journal for Research Trends and Innovation
International Peer Reviewed & Refereed Journals, Open Access Journal
ISSN Approved Journal No: 2456-3315 | Impact factor: 8.14 | ESTD Year: 2016
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Impact Factor : 8.14
Issue per Year : 12
Volume Published : 11
Issue Published : 118
Article Submitted : 21609
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Total Authors : 22438
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| Paper Title: | Tungustophosphoric acid catalyzed oxidation of some α-amino acids by N-chlorosuccinimide |
| Authors Name: | Anamika Singh , H.P. Dwivedi |
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IJRTI_185059
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| Published Paper Id: | IJRTI2301015 |
| Published In: | Volume 8 Issue 1, January-2023 |
| DOI: | |
| Abstract: | We describe the tungustophosphoric acid (Keggin anion type) catalyzed oxidation of a couple of ℓ-alanine and ℓ-leucine by N-chlorosuccinimide in aqueous acetic acid medium resulting to the formation of corresponding aldehydes. The reaction proceeds through formation of transient existence of ternary complex in equilibrium state. The ternary complex in equilibrium state. The stoichiometry (∆[NCS])/([α-amino acid]) (1:1) is in good agreement supported by rate law as first-order to [NCS] oxidant and fractional-order each to [TPA], [H+] and [ℓ-amino acids]. The participation of Zwitter ion and postulated reacting species HOCl was involved in the proposed plausible mechanism. The role of activation parameters was discussed in favour of mechanism. |
| Keywords: | Tungustophosphoric acid, ℓ-alanine, ℓ-leucine, N-chlorosuccinimide, oxidation |
| Cite Article: | "Tungustophosphoric acid catalyzed oxidation of some α-amino acids by N-chlorosuccinimide", International Journal for Research Trends and Innovation (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.83 - 87, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301015.pdf |
| Downloads: | 000205363 |
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016 An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator |
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Published Paper ID: IJRTI2301015
Registration ID:185059
Published In: Volume 8 Issue 1, January-2023
DOI (Digital Object Identifier):
Page No: 83 - 87 Country: -, -, - Research Area: Other Publisher : IJ Publication Published Paper URL : https://www.ijrti.org/viewpaperforall?paper=IJRTI2301015 Published Paper PDF: https://www.ijrti.org/papers/IJRTI2301015 |
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ISSN: 2456-3315
Impact Factor: 8.14 and ISSN APPROVED,
Journal Starting Year (ESTD) : 2016
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