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In this perspective, the oxidation of acetyl acetone (AA) and benzoyl acetone (BA) in aqueous acetic acid in presence of mineral acid by QDC leads to the formation of corresponding pentane-2,3,4-tione and 1-phenyl butane-1,2,3-trione. The reaction follows first-order kinetic in low concentration of QDC. The rate varies direct proportionality to low concentrations of diketones, which tends to become, zero order at its higher concentrations. The catalytic data of rate is satisfied for the first-order in H+ ion. The stoichiometry (2:3) was measured for the reactions. The protonated form of QDC species attacks at enolic form of organic substrate. The activation parameters and rate law of the oxidation reactions were derived that suggested the plausible reaction mechanism.
"Study of Oxidation of Diketones by Quinolinium Dichromate", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.302 - 305, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301048.pdf
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
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