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We describe the tungustophosphoric acid (Keggin anion type) catalyzed oxidation of a couple of ℓ-alanine and ℓ-leucine by N-chlorosuccinimide in aqueous acetic acid medium resulting to the formation of corresponding aldehydes. The reaction proceeds through formation of transient existence of ternary complex in equilibrium state. The ternary complex in equilibrium state. The stoichiometry (∆[NCS])/([α-amino acid]) (1:1) is in good agreement supported by rate law as first-order to [NCS] oxidant and fractional-order each to [TPA], [H+] and [ℓ-amino acids]. The participation of Zwitter ion and postulated reacting species HOCl was involved in the proposed plausible mechanism. The role of activation parameters was discussed in favour of mechanism.
"Tungustophosphoric acid catalyzed oxidation of some α-amino acids by N-chlorosuccinimide", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.83 - 87, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301015.pdf
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
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