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Kinetic investigation in Ru(III) catalysed oxidation of mannitol by N-chlorophthalimide in aqueous acetic acid medium in presence of HCl have been carried out. The influence of Ru(III) shows a first-order dependence on [NCP] and fractional-order each on (Ru(III)[ and [H+]. The rate was verified for Michaelis-Menten type kinetics. The variation of ionic strength and phthalimide (reaction product) have negligible effect on rate. The negative effect with acrylonitrile could also be observed. On the basis of observed results, two schemes of scanty mechanism are proposed. One as acid dependent and another acid independent paths. Activation parameters for the reaction have been evaluated at different temperatures in conformity with the derived rate law.
"Ruthenium(III) Catalyzed Oxidation of Mannitol by N-chlorophthalimide", International Journal of Science & Engineering Development Research (www.ijrti.org), ISSN:2455-2631, Vol.8, Issue 1, page no.55 - 59, January-2023, Available :http://www.ijrti.org/papers/IJRTI2301010.pdf
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2456-3315 | IMPACT FACTOR: 8.14 Calculated By Google Scholar| ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 8.14 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
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